Kinetics and Mechanism of Oxidation of D(+)-Sorbose by Chloramine-T

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概要

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• The kinetics of oxidation of D(+)-sorbose by chloramine-T has been investigated in high alkaline media. The reaction shows a brief induction period after which a first order dependence in both chloramine-T and substrate is followed. The order in hydroxide ion is observed as fractional being 1.3 under the experimental conditions. The values of energy of activation, frequency factor and entropy of activation have been computed as 28.2 kcal mol<SUP>−1</SUP>, 2.90×10<SUP>19</SUP> 1 mol<SUP>−1</SUP> s<SUP>−1</SUP> and +29.8 e.u. respectively. A plausible mechanism consistent to the experimental result is proposed.

• 公益社団法人 日本化学会の論文

著者

• Gupta K.

  Chemical Laboratories, University of Allahabad

• Sanehi R.

  Chemical Laboratories, University of Allahabad

• Mehrotra R.

  Chemical Laboratories, University of Allahabad

• Mushran S.

  Chemical Laboratories, University of Allahabad

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• Kinetics and Mechanism of Oxidation of D(+)-Sorbose by Chloramine-T

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