Polarographic Study of Catalytic Reduction of Tris(2,2′-bipyridine)-copper(II) in the Presence of Nitrite Ion

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概要

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• The rigorously derived equation for a catalytic current was applied to the evaluation of the rate constant for the oxidation reaction of bis(2,2′-bipyridine)copper(I) by nitrite ion by use of a computer and subroutine program for the curve-fitting method. This method made it possible to calculate the rate constant from low limiting current in the presence of nitrite ion. The rate in acetate buffer solutions has first-order dependence on each reactant and hydrogen ion, and the apparent rate constant is 1×10<SUP>6</SUP> M<SUP>−2</SUP> s<SUP>−1</SUP> at 25 °C.

• 公益社団法人 日本化学会の論文

著者

• Tanaka Kazuyoshi

  Department of Chemistry, College of Science, Rikkyo University

関連論文

• Polarographic Study of Catalytic Reduction of Tris(2,2′-bipyridine)-copper(II) in the Presence of Nitrite Ion

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