Interactions of 1-Substituted 2,4-Dinitrobenzenes with Methoxide and Hydroxide Ions in Dimethyl Sulfoxide with a Rapid Scan Spectrophotometer

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概要

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• The interactions of <I>m</I>-dinitrobenzene and 1-substituted 2,4-dinitrobenzenes with sodium methoxide in meth-anolic dimethyl sulfoxide were studied with a rapid scan spectrophotometer. A similar study of 1-substituted 2,4-dinitrobenzenes with sodium hydroxide in aqueous dimethyl sulfoxide was carried out. Except for a few cases, the first transient colored-complexes of 3-substituted 2,6-dinitrocyclohexadienates were observed at initial stages before the complete formation of second colored-complexes having the π-electronic structures of 1,3-dinitropentadienyl anion.

• 公益社団法人 日本化学会の論文

著者

• Hasegawa Yoshinori

  College of General Education, Tohoku University

関連論文

• Interactions of 1-Substituted 2,4-Dinitrobenzenes with Methoxide and Hydroxide Ions in Dimethyl Sulfoxide with a Rapid Scan Spectrophotometer
• Near Ultraviolet Absorption Spectrum of Pyridine-d5 Vapor

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