Micellar Effect of Alkylammonium Propionates on Reaction Rate of Keto-Enol Tautomerism in Cyclohexane
スポンサーリンク
概要
- 論文の詳細を見る
The rate of keto-enol transformation of acetylacetone or acetoethyl acetate was spectroscopically measured in the cyclohexane solutions in the presence of primary, secondary or tertiary alkylammonium propionate. The rate was enhanced by micelle formed. The order of effectiveness of the surfactants was that primary>>secondary> tertiary. The order coincides with the number of protons in the ammonium ion of the surfactants and the aggregation number of micelle.
- 公益社団法人 日本化学会の論文
著者
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Kon-no Kijiro
Department Of Industrial Chemistry Faculty Of Engineering Science University Of Tokyo
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Kitahara Ayao
Department Of Engeering Chemistry Faculty Of Engeneering Science University Of Tokyo
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Kon-No Kijiro
Department of Industrial Chemistry, Science University of Tokyo
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Miyazawa Kiyoshi-
Department of Industrial Chemistry, Science University of Tokyo
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Kitahara Ayao
Department of Industrial Chemistry, Science University of Tokyo
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