An Electron Spin Resonance Study of Some Quadridentate Schiff Base Complexes of Copper(II)
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概要
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The X-band ESR spectra of a series of quadridentate Schiff base complexes of copper(II) have been examined in frozen xylene and chloroform solutions. Well resolved triplet state spectra were observed both at <I>g ca.</I> 2 and <I>g ca.</I> 4 due to dimeric forms of these complexes which exist in frozen solution. Magnetic and structural parameters have been determined by computer simulation of the triplet state spectra based on a lower than axial symmetry model for the copper(II) pair system.
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