The Thermal Decomposition Reactions of Bivalent Metal Succinates in the Solid State
スポンサーリンク
概要
- 論文の詳細を見る
The thermal decomposition reactions of MC<SUB>4</SUB>H<SUB>4</SUB>O<SUB>4</SUB> (M : Mg(II), Co(II), Ni(II), Cu(II), Zn(II), and Pb(II)) in nitrogen or helium were investigated by means of TG-DTA, X-ray diffraction measurements, gas chromatography, and combustion analysis for carbon. The decomposition residues of the Mg and Zn salts were composed of the corresponding metal oxides and some carbon, while those of the Co, Ni, Cu, and Pb salts were composed of the corresponding metals and some carbon. H<SUB>2</SUB>, O<SUB>2</SUB>, CO, CO<SUB>2</SUB>, H<SUB>2</SUB>O, CH<SUB>4</SUB>, C<SUB>2</SUB>H<SUB>2</SUB>, C<SUB>2</SUB>H<SUB>4</SUB>, HCOOCH<SUB>3</SUB>, HCOOC<SUB>2</SUB>H<SUB>5</SUB>, CH<SUB>3</SUB>COOC<SUB>2</SUB>H<SUB>5</SUB>, C<SUB>2</SUB>H<SUB>5</SUB>COOC<SUB>2</SUB>H<SUB>5</SUB>, and (CH<SUB>2</SUB>CO)<SUB>2</SUB>O were identified as the gaseous decomposition products; the compositions of the gaseous mixtures varied a great deal with the metals. Possible reaction mechanisms were discussed mainly on the basis of the decomposition products.
- 公益社団法人 日本化学会の論文
著者
-
Muraishi Kazuo
Department of Chemistry, Faculty of Science, Yamagata University
-
Nagase Kenzo
College of General Education, Tohoku University
-
Yokobayashi Hiroko
College of General Education, Tohoku University
関連論文
- The Structures and Thermal Behaviors of Bivalent Metal Succinates in the Solid State
- Influences of the lanthanoid contraction on the thermal dehydration reactions of lanthanoid(III) malonate hydrates.
- Thermal Dehydration and Decomposition of Dioxalato Complexes of Be(II), Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) in Solid State
- The Thermal Decomposition Reactions of Bivalent Metal Succinates in the Solid State
- Thermal dehydration reactions of bivalent transition metal malonate dihydrates in solid state.
- Syntheses and thermal properties of some bivalent transition metal complexes with 1,4-diazabicyclo[2.2.2]octane.