Dehydrobromination of 16-Bromodihydroenmein-type Compounds
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16-Bromodihydroenmein diacetate (IV) obtained from dihydroenmein diacetate (III) by bromination with <I>N</I>-bromosuccinimide was dehydrobrominated with lithium chloride in dimethylformamide to give a product, the structure of which was elucidated as the intermolecular ether (VIII). The dimeric ether compound was also formed by similar reactions from the derivative of isodocarpin.
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