Reactions of 1,8-Dehydronaphthalene with Cyclic Polyenes

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概要

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• The reactivities of 1,8-dehydronaphthalene (<B>1</B>) to cyclic polyenes, <I>i.e.</I>, cycloheptatriene, cyclopentadiene, 6,6-dimethylfulvene, furan, and norbornadiene, were examined. It was found that the C–H insertion reaction at the end of the conjugated systems, a new type of reaction of <B>1</B>, as well as the 1,2-cycloaddition reaction occurs in every conjugated cyclic polyene. A stepwise mechanism for the formation of the C–H insertion product was proposed.

• 公益社団法人 日本化学会の論文

著者

• Takaoka Shigeru

  Faculty of Science, Osaka City University

関連論文

• Reactions of 1,8-Dehydronaphthalene with Cyclic Polyenes

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