The Synthesis of Heterocyclic Compounds by the Reaction of Tin(II) Bis(acetylacetonate) with Isocyanates

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概要

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• It was found that phenyl isocyanate reacted with tin(II) bis(acetylacetonate) to yield triphenyl isocyanurate, 5-acetyl-6-methyl-2-oxo-3-phenyl-4-phenylimino-3,4-dihydro-2<I>H</I>-1,3-oxazine, and <I>N</I>,<I>N</I>′-diphenylurea, while ethyl isocyanate reacted with tin(II) bis(acetylaceonate) to afford only 2,4-dioxo-6-ethylimino-1,3,5-triethylhexahydro-1,3,5-triazine.

• 公益社団法人 日本化学会の論文

著者

• Kijima Ichiro

  Department Of Industrial Chemistry Science University Of Tokyo

• Wakeshima Ikuko

  Department of Industrial Chemistry, Faculty of Engineering, Science University of Tokyo

関連論文

• Formation of 2,6-Naphthalenedicarboxylic Acid by the Co-Mn-Br-Catalyzed Autoxidation of 2,6-Diethylnaphthalene in Acetic Acid
• Reaction of organic tin(II) compound with phenyl isothiocyanate and carbon disulfide.
• Alkoxysilanes. V. The Preparation of Polyalkyl(aryl) Silicates
• Reaction of organic tin(II) compound with carbonyl compound.
• Alkoxysilanes. IV. Preparation of Alkoxysiloxy Derivatives of Titanium
• The Cyclic Trimerization of Isocyanates by Organic Tin(II) Compounds Containing Sn–O–C Bonds
• The Synthesis of Heterocyclic Compounds by the Reaction of Tin(II) Bis(acetylacetonate) with Isocyanates

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