Carbonylation of saturated hydrocarbons catalyzed by copper(I) carbonyls in FSO3H-Sb5F.

スポンサーリンク

概要

• 論文の詳細を見る

• Saturated hydrocarbons react with carbon monoxide in the presence of copper(I) carbonyl catalysts in FSO<SUB>3</SUB>H-SbF<SUB>5</SUB>. Tertiary-carboxylic acid and secondary-carboxylic acid were obtained in high yields at −2 to +2 °C and at 1 atm of carbon monoxide. For the isomerization process of intermediate carbonium ions, the cleavage of the C–C bond was recognized, and stable <I>t</I>-butyl cations were formed.

• 公益社団法人 日本化学会の論文

著者

• Souma Yoshie

  Government Industrial Research Institute

• Sano Hiroshi

  Government Industrial Research Institute, Osaka

• Sano Hiroshi

  Government Industrial Research Institute

関連論文

• Carbonylation of saturated hydrocarbons catalyzed by copper(I) carbonyls in FSO3H-Sb5F.
• Carbonylation of olefins, alcohols, and saturated hydrocarbons using Cu(CO)n+ and Ag(CO)2+ catalysts in BF3-H2O.
• Carbonylation of Alcohols, Olefins, and Saturated Hydrocarbons by CO in the Ag(I)–H2SO4 System
• The Carbonylation of Alcohols Catalyzed by Cu(I) Carbonyl

スポンサーリンク