The reactions of sodium diethyldithiocarbamate and tetraethylthiuram disulfide with mercury(II) chloride.

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概要

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• Sodium diethyldithiocarbamate (<B>1</B>) and tetraethylthiuram disulfide (<B>2</B>) have been found to react with excess mercury(II) chloride (HgCl<SUB>2</SUB>) in water to give complexes with the general formula Et<SUB>2</SUB>NCS<SUB>2</SUB>HgS<SUB>2</SUB>CNEt<SUB>2</SUB>·(HgCl<SUB>2</SUB>)<SUB><I>m</I>−1</SUB>, where the <I>m</I> value can be as high as five. The complex with <I>m</I>=2 was isolated and characterized. The reaction pathway was discussed in some detail. Also studied were the reactions of <B>2</B> with HgCl<SUB>2</SUB> in organic solvents.

• 公益社団法人 日本化学会の論文

著者

• Fujisawa Tamotsu

  Sagami Chemical Research Center

• Kobayashi Norio

  Sagami Chemical Research Center

関連論文

• The reactions of sodium diethyldithiocarbamate and tetraethylthiuram disulfide with mercury(II) chloride.
• Sulfur-containing Polymers. XIII. The Synthesis and Properties of Soluble Polydithiocarbamates
• Rearrangement of Aryl Sulfides in the Presence of Aluminum Chloride

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