Solid-state circular dichroism spectra of tris(diamine)cobalt(III) complexes: Decomposition into E and A2 components.

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概要

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• Solid-state circular dichroism spectra of some tris(diamine) cobalt(III) complexes were measured. Each CD band region was decomposed into E and A<SUB>2</SUB> components by combining the CD spectra in uniaxial single-crystals and in microcrystalline states. The observed values of <I>R</I>(E) and <I>R</I>(A<SUB>2</SUB>) were compared with the theoretical calculation of Mason and Seal based on dynamic coupling method. The agreements are generally good for those complexes with five-membered chelate rings, however, there are some discrepancies for six- and seven-membered chelate ring cases.

• 公益社団法人 日本化学会の論文

著者

• Saito Yoshihiko

  The Institute for Solid State Physics The University of Tokyo

• Saito Yoshihiko

  The Institute for Solid State Physics, The University of Tokyo

• Kuroda Reiko

  The Institute for Solid State Physics, The University of Tokyo

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