The preparation and characterization of isomers of (amino acidato)-(iminodiacetato)nitrocobaltate(III)(1-) complexes.

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概要

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• Three geometrical isomers of <I>fac(ida)</I>-[Co(NO<SUB>2</SUB>)(gly)(ida)]<SUP>−</SUP> have been prepared and optically resolved (gly=glycinato(1–) and ida=iminodiacetato(2–) ligand), and their configurations were determined from the visible and ultraviolet absorption, and circular dichroism spectra. A diastereomeric pair was obtained for the corresponding L-alaninato, L-serinato, or L-prolinato complex.

• 公益社団法人 日本化学会の論文

著者

• KAIZAKI Sumio

  Department of Chemistry, Faculty of Science, Osaka University

関連論文

• The preparation and characterization of isomers of (amino acidato)-(iminodiacetato)nitrocobaltate(III)(1-) complexes.

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