Aromatic nucleophilic substitution. VI. 1H nuclear magnetic resonance evidence for the rearrangement of 1,3- to 1,1-anionic .SIGMA. complex in the reactions of 1-dialkylamino-2,4-dinitronaphthalenes with potassium alkoxides.

スポンサーリンク

概要

• 論文の詳細を見る

• By use of NMR spectroscopy the rearrangement of 1,3- to 1,1-anionic σ complex (Meisenheimer complex) in the reactions of 1-dialkylamino-2,4-dinitronaphthalenes (dimethylamino-, diethylamino-, and <I>N</I>-methyl-<I>N</I>-butylamino, piperidyl) with potassium alkoxides in DMSO has been studied. The alkoxides used are potassium methoxide, ethoxide, isopropoxide, and <I>t</I>-butoxide. In the reactions of 1-dialkylamino-2,4-dinitronaphthalenes with the alkoxides the rearrangement could be spectrometrically analyzed. However, in the reaction of 1-dimethylamino-2,4-dinitro naphthalene with potassium <I>t</I>-butoxide the rearrangement was too fast to be clearly analyzed.

• 公益社団法人 日本化学会の論文

著者

• Ando Yumiko

  Synthetic Chemistry Department, Gunma University

• Sekiguchi Shizen

  Synthetic Chemistry Department, Gunma University

• Fujisawa Shigeru

  Synthetic Chemistry Department, Gunma University

関連論文

• Aromatic nucleophilic substitution. VI. 1H nuclear magnetic resonance evidence for the rearrangement of 1,3- to 1,1-anionic .SIGMA. complex in the reactions of 1-dialkylamino-2,4-dinitronaphthalenes with potassium alkoxides.

スポンサーリンク