Synthesis of 2,7-di-t-butyl-4,5,9,10-tetraphenyltricyclo[6.2.0.03,6]deca-1,3(6),4,7,9-pentaene. A benzo[1,2:4,5]dicyclobutene.
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概要
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The title compound (<B>15</B>) which has two cyclobutadienes fused to a benzene ring, was synthesized by heating <I>dl</I>- (<B>7</B>), <I>meso</I>-3,8-di-<I>t</I>-butyl-1,5,6,10-tetraphenyldeca-3,4,6,7-tetraene-1,9-diyne (<B>8</B>), or <I>E</I>,<I>Z</I>,-3,4-bis (1-<I>t</I>-butyl-3-phenyl-2-propynylidene)-1,2-diphenyl-1-cyclobutene (<B>12</B>).
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- Synthesis of 2,7-di-t-butyl-4,5,9,10-tetraphenyltricyclo[6.2.0.03,6]deca-1,3(6),4,7,9-pentaene. A benzo[1,2:4,5]dicyclobutene.