The synthesis of several octose derivatives related to octosyl acids A and B.

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概要

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• Starting from 1,2: 5,6-di-<I>O</I>-isopropylidene-α-D-allofuranose (<B>3a</B>), the sugar portion of octosyl acids <B>A</B> and <B>B</B> (<B>1a</B> and <B>1b</B>) was synthesised, though with some protecting groups. Compound <B>7a</B>, thus obtained, was found to be acid-liable, and treatment of <B>7a</B> in a dilute hydrochloric acid in methanol resulted in furanose-ring opening, affording an isopropylidene compound <B>8</B>.

• 公益社団法人 日本化学会の論文

著者

• Anzai Kentaro

  The Institute of Physical and Chemical Research

• Saita Tsuneo

  The Institute of Physical and Chemical Research

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