The synthesis of 3-substituted tropilidenes by the dehydration of 1-substituted 2,6-cycloheptadienols. A new unambiguous route.
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概要
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3-Alkyl-, 3-aryl-, and 3-deuteriotropilidenes are prepared in 21–29% yields by the dehydration of the corresponding 1-substituted 2,6-cycloheptadienols with boric acid. The present method provides an unambiguous route to the title compounds.
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