Ultraviolet spectral study of o- and p-(halomercurio)phenols.
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概要
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The ultraviolet spectra of <I>o</I>- and <I>p</I>-(halomercurio)phenols, <I>o</I>- and <I>p</I>-OHC<SUB>6</SUB>H<SUB>4</SUB>HgX(X=F, Cl, Br, or I) have been recorded in ethanolic solution and λ<SUB>max</SUB> and logε<SUB>max</SUB> have been recorded. The spectra of these compounds have been interpreted in terms of the correlation with the spectra of benzene. HgX group is shown to be having electron-withdrawing effect on the benzene ring. Variation in the values of λ<SUB>max</SUB> and logε<SUB>max</SUB> on changing from <I>o</I>- to <I>p</I>-derivative for a particular (halomercurio)phenol and on changing the halogen attached to mercury has been explained.
- 公益社団法人 日本化学会の論文
著者
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Yadav P.
Department Of Botany Andhra University
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Yadav P.
Department of Chemistry
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Jha N.
Department of Chemistry
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Ramakrishna V.
Department of Chemistry
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- Ultraviolet spectral study of o- and p-(halomercurio)phenols.