The halogenation and nitration of the optical active isomer of the .ALPHA.-acetylacetonato(triethylenetetramine)cobalt(III) complex.

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概要

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• The methylidyne hydrogen of the coordinated acetylacetonate ion in (+)<SUB>D</SUB>-α-acetylacetonato(triethylenetetramine)cobalt(III) perchlorate has been replaced with halogens and with a nitro group with a complete retention of the configuration. The order of the molar rotations of the complexes has been found to be: acac-<Clacac-<Bracac-<Iacac-complex and acac-\simeqO<SUB>2</SUB>Nacac-complex.

• 公益社団法人 日本化学会の論文

著者

• Yamaoka Noriko

  Department Of Analytical Chemistry School Of Pharmaceutical Sciences Teikyo University

• Yamaguchi Kazumi

  Department of Chemistry, Faculty of Science, Ehime University

• Kuroda Kashiro

  Department of Chemistry, Faculty of Science, Ehime University

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