Fluorination with substituted (difluoroiodo)arenes.
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概要
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The reaction of substituted (difluoroiodo)arenes with 1-phenyl-1-(<I>m</I>-chlorophenyl)ethylene results in 1,1-difluoro-1-(<I>m</I>-chlorophenyl)2-phenylethane, with 1-phenyl-1-(<I>p</I>-methoxyphenyl)ethylene in 1,1-difluoro-1-phenyl-2-(<I>p</I>-methoxyphenyl) ethane, and with 1-phenylcyclopentene and 1-phenylcyclohexene in rearranged <I>gem</I>-difluoro compounds. The reaction with norbornene results in three products: fluoronortricyclane (9–12%), 2-<I>exo</I>-7-<I>syn</I>-difluoronorbornane (75–86%), and 2-<I>exo</I>-7-<I>anti</I>-difluoronorbornane (5–15%) depending upon the substituent on the phenyl ring in (difluoroiodo)arenes.
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著者
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Zupan Marko
"J. Stefan" Institute and Department of Chemistry, University of Ljubljana
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Gregorcic Ana
"J. Stefan" Institute and Department of Chemistry, University of Ljubljana
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Zupan Marko
"J. Stefan" Institute and Department of Chemistry, University of Ljubljana