V-51 and Mn-55 NMR studies of metal carbonyls.

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概要

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• The metal chemical NMR shifts of metal carbonyls are reported and discussed in relation to the bonding nature characteristic of carbonyl compounds of the M(CO)<SUB>6</SUB>- and Mn(CO)<SUB>5</SUB>X-types, where M is V or Mn, and X is a halogen or SCN. Theoretically evaluated chemical shift data based upon Ramsey's expression agree well with those observed for the M(CO)<SUB>6</SUB>-type carbonyls. Regarding Mn(CO)<SUB>5</SUB>X, the variation of the shifts for halogens is elucidated theoretically and revealed to be dependent upon the π-bonding nature between the metal and the halogen atom.

• 公益社団法人 日本化学会の論文

著者

• Nakano Taku

  Department of Chemistry, Faculty of Sciences, The University of Tokyo

• Nakano Taku

  Department of Chemistry, Faculty of Science, The University of Tokyo

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• V-51 and Mn-55 NMR studies of metal carbonyls.

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