Preparation and the acid hydrolysis of N-(2-hydroxyethyl)ethylene-diamine-N,N',N'-triacetate complex of di-.MU.-oxo-bis-(oxomolybdenum(V)).

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概要

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• A hedta (H<SUB>3</SUB>hedta=<I>N</I>-(2-hydroxyethyl)-ethylenediamine-<I>N</I>,<I>N</I>′,<I>N</I>′-triacetic acid) complex of molybdenum(V), Mo<SUB>2</SUB>O<SUB>4</SUB>(hedta)(H<SUB>2</SUB>O)<SUP>−</SUP>, has been prepared and characterized. The rate of acid hydrolysis of this complex in an aqueous perchloric acid solution ([H<SUP>+</SUP>]=0.5–2.0 mol dm<SUP>−3</SUP>; <I>I</I>=2.0) is of similar magnitude to that of Mo<SUB>2</SUB>O<SUB>4</SUB>(edta)<SUP>2−</SUP>(H<SUB>4</SUB>edta=ethylenediaminetetraacetic acid), increasing with increase in [H<SUP>+</SUP>].

• 公益社団法人 日本化学会の論文

著者

• Morita Tomoji

  Chemistry Department, Faculty of Science, Tohoku University

• Sasaki Yoichi

  Chemistry Department, Faculty of Science, Tohoku University

関連論文

• Preparation and the acid hydrolysis of N-(2-hydroxyethyl)ethylene-diamine-N,N',N'-triacetate complex of di-.MU.-oxo-bis-(oxomolybdenum(V)).

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