Hydrogen isotope effect on the radical addition of the hydrogensulfite ion to allyl alcohol in aqueous solutions.

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概要

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• A study of the radiation-induced addition of HSO<SUB>3</SUB><SUP>−</SUP> to allyl alcohol was carried out in D<SUB>2</SUB>O–H<SUB>2</SUB>O mixtures. It was found that a linear relationship held between the apparent rate constant of NaHSO<SUB>3</SUB> consumption and the atom fraction of deuterium in the mixture, and that the hydrogen atom abstraction from HSO<SUB>3</SUB><SUP>−</SUP> by HOCH<SUB>2</SUB>\dotCH-CH<SUB>2</SUB>SO<SUB>3</SUB><SUP>−</SUP> was the rate-determining step. The kinetic isotope effect of this abstraction was 4.38.

• 公益社団法人 日本化学会の論文

著者

• Miyata Teijiro

  Japan Atomic Energy Research Institute

• Sakumoto Akihisa

  Japan Atomic Energy Research Institute

• Washino Masamitsu

  Japan Atomic Energy Research Institute

関連論文

• The Radiation-induced Decoloration of Azo Dye in Aqueous Solutions
• The radiolysis of anthraquinone dye in aqueous solutions.
• Hydrogen isotope effect on the radical addition of the hydrogensulfite ion to allyl alcohol in aqueous solutions.
• The kinetics and mechanism of the radical addition of hydrogensulfite ions to 1-dodecene in a micellar solution of sodium 1-dodecanesulfonate.
• pH effects on the radical addition of hydrogensulfite ion to olefins.
• The effects of halide ions on the radiation-induced decoloration of azo and anthraquinone dyes in N2O-saturated aqueous solutions.
• Measurements of Optical Absorption Spectra under 60Co-γ Irradiation. Aqueous Methylene Blue Solutions Containing Oxygen

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