Infrared spectra of 1,3-butadiene adsorbed on alumina-supported metal catalysts at various temperatures.
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概要
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The infrared spectra of 1,3-butadiene adsorbed on Pd, Ni, and Co catalysts were measured while changing the adsorption temperature. These catalysts behaved differently in butadiene adsorption, and π-adsorbed butadiene was the major adsorbed species below 0 °C on Pd and Ni. This π-species was easily hydrogenated to produce butene at the same temperature.
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