Determination of micropore volumes of active carbon using dubinin-radushkevich plots.
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概要
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The adsorption of methanol on active carbons at 30 °C was carried out and a new method for determining the micropore volume in the Dubinin-Radushkevich plot is presented. From this method, it was found that the adsorption volume (<I>V</I>) corresponding to the adsorption potential (<I>A</I>=<I>RT</I>ln<I>P</I><SUB>0</SUB>⁄<I>P</I>), at which the plot of <I>dV</I>⁄<I>d</I>(−<I>A</I>) <I>vs.</I> A has its minimum value, is the value of the micropore volume in cases where extrapolation of the Dubinin-Radushkevich plot cannot be applied because of non-linearity of the Dubinin-Radushkevich plot.
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