The structure of ikarugamycin, an acyltetramic acid antibiotic possessing a unique as-hydrindacene skeleton.

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概要

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• The structure and configuration of an antibiotic, ikarugamycin, have been established to be <B>1e</B> on the basis of chemical reactions, especially of oxidative degradation. It is suggested that the <I>as</I>-hydrindacene skeleton arises biogenetically <I>via</I> an intramolecular Diels-Alder reaction.

• 公益社団法人 日本化学会の論文

著者

• Hirata Yoshimasa

  Department of Chemistry, Faculty of Science, Nagoya University

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