The photoreaction of 1-cycloalkenyl phenethyl ketone.

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概要

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• The UV irradiation of 1-cyclopentenyl phenethyl ketone in benzene or methanol gave a cyclobutane derivative. The irradiation of 1-cyclohexenyl phenethyl ketone in methanol or in benzene containing either BF<SUB>3</SUB>–Et<SUB>2</SUB>O or CF<SUB>3</SUB>COOH gave a cycloheptanone derivative. The formation of the cycloheptanone derivative requires an acid catalyst.

• 公益社団法人 日本化学会の論文

著者

• Miura Kyo

  Department of Chemistry, School of Science and Engineering, Waseda University

関連論文

• The photoreaction of benzyl 1-cycloalkenyl ketone in acidic or protic media.
• The photo-cycloaddition of 3-cyano-2,4-pentanedione with cyclohexene and its quenching by enol ether.
• Reaction of bis(dimethylglyoximato)(pyridine)styrylcobalt(III) derivatives with arenesulfenyl chloride.
• The photoreaction of 1-cycloalkenyl phenethyl ketone.

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