The Chromium(VI) Oxide Oxidation of Epimeric 1,2,3,4-Tetrahydro-1-naphthols
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概要
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The rates of the chromium(VI) oxide oxidation of 2- and 3-substituted 1-tetralols(1,2,3,4-tetrahydro-1-naphthols) have been determined. In the 3-substituted compounds, the rates of <I>cis</I>-isomers(eq'-OH) are markedly larger than those of <I>trans</I>-isomers(ax'-OH). On the other hand, in the case of 2-substituted compounds, the rates of the <I>cis</I>-isomers(ax'-OH) and <I>trans</I>-homers (eq'-OH) are almost equal.
- 公益社団法人 日本化学会の論文
著者
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Kudo Hideaki
Department Of Anatomy University Of Occupational And Environmental Health School Of Medicine
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Hanaya Kaoru
Department of Chemistry, Faculty of Science, The University of Tokyo
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Awano Sachio
Department of Chemistry, Faculty of Science, Yamagata University
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