Correlation of solvation free energy of electron with empirical parameters of solvents. A criterion for electrophilic effects of solvents.
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概要
- 論文の詳細を見る
The solvation free energy of electrons in <I>N</I>,<I>N</I>-dimethylformamide, methanol, and water was estimated by means of electron photoemission into solution, and the data were compared with empirical parameters such as thermodynamic quantities, structural and kinetic parameters of solvents. It was confirmed that the interaction of an electron with solvent molecules is purely electrostatic and that the solvation free energy can be used as a tentative criterion of electrophilic properties of solvents.
- 公益社団法人 日本化学会の論文
著者
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Yamashita Kazuo
Faculty Of Integrated Arts And Sciences Hiroshima University
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Imai Hideo
Faculty of Integrated Arts and Sciences, Hiroshima University
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- Correlation of solvation free energy of electron with empirical parameters of solvents. A criterion for electrophilic effects of solvents.