The relative rates of ene reaction of benzyne with cyclic olefins: The stereochemical course.

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概要

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• The benzyne reaction of cyclic olefins, in competition with that of cyclohexene has been studied. The relative reactivities for ene reaction and the stereoselectivity of the reaction with 4-<I>t</I>-butylcyclohexene, which afforded <I>trans</I>-5-<I>t</I>-butyl-3-phenylcyclohexene and <I>cis</I>-3-<I>t</I>-butyl-6-phenylcyclohexene, are consistent with the stereochemical requirements along the reaction pathway.

• 公益社団法人 日本化学会の論文

著者

• Kato Masahiko

  Faculty Of Engineering Hiroshima University

• Okamoto Yukio

  Wakayama Technical College

• Chikamoto Takeji

  Faculty of Science, Osaka City University

• Miwa Toshio

  Faculty of Science, Osaka City University

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