Five-coordinate bis(8-aminoquinoline) nitrosylcobalt complexes.

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概要

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• [Co(C<SUB>9</SUB>H<SUB>8</SUB>N<SUB>2</SUB>)<SUB>2</SUB>NO]X<SUB>2</SUB>·<I>n</I>H<SUB>2</SUB>O (C<SUB>9</SUB>H<SUB>8</SUB>N<SUB>2</SUB>=8-aminoquinoline; X=Cl, Br, I, NO<SUB>3</SUB>, ClO<SUB>4</SUB>, and SO<SUB>4</SUB>/2; <I>n</I>=0, 1, 1.5, and 2) was isolated by the reaction of nitrogen oxide with a mixture of the corresponding cobalt(II) salt and 8-aminoquinoline in methanol. The IR, UV, and molar conductivity measurements suggest that the geometry of the cation is a tetragonal pyramid with an apical NO<SUP>−</SUP>.

• 公益社団法人 日本化学会の論文

著者

• Okamura Hiromichi

  Department of Chemistry, College of Science, Rikkyo University

関連論文

• Potassium .MU.-(trans-hyponitrito-N,N')-bis{pentacyanocobaltate(III)} and potassium .MU.-(trans-hyponitrito-O,O')-bis-{pentacyanocobaltate(III)}.
• Five-coordinate bis(8-aminoquinoline) nitrosylcobalt complexes.

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