Synthesis of oxide-chalcogenides. I. Hydrothermal synthesis of sarabauite CaSb10O10S6 and related compounds.

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概要

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• Single crystals of a recently described metal oxide sulfide mineral sarabauite and three related oxide-sulfides of alkaline earths and antimony were hydrothermally synthesized. (1) CaSb<SUB>10</SUB>O<SUB>10</SUB>S<SUB>6</SUB>: color, carmine red; crystal system, monoclinic; space group, C2/c. (2) Compound in Sr–Sb–O–S system (O<S), blackish silver, monoclinic, P2<SUB>1</SUB>/a. (3) Compound in Ba-S–b–O–S system (O>S), reddish orange, triclinic P1 or P\bar1. (4) Compound in Ba–Sb–S–O system (O<S), blackish brown, monoclinic, P2<SUB>1</SUB>/a.

• 公益社団法人 日本化学会の論文

著者

• NAGASHIMA Kozo

  Department of Chemistry, the University of Tsukuba

関連論文

• A rietveld analysis of the crystal structure of ammonioleucite
• Synthesis of oxide-chalcogenides. I. Hydrothermal synthesis of sarabauite CaSb10O10S6 and related compounds.

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