The effect of the vibrational and translational energies of ionic reactant on the reaction C3H4++NH3.RAR.C3H3+NH4+.

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概要

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• The effect of the internal and translational energies of ionic reactant on the rates of the reactions C<SUB>3</SUB>H<SUB>4</SUB><SUP>+</SUP>+NH<SUB>3</SUB>→C<SUB>3</SUB>H<SUB>3</SUB>+NH<SUB>4</SUB><SUP>+</SUP> has been examined by producing the reactant ions from propyne, allene, and cyclopropene by photoionization at various wavelengths. The translational energy was varied by changing the repeller voltage in the ionization chamber. The cross sections for all the reactions decreased with an increase in the internal energy at all the translational energies studied. The results have been explained in terms of the complex mechanism.

• 公益社団法人 日本化学会の論文

著者

• Honma Kenji

  Department of Chemistry, Tokyo Institute of Technology

関連論文

• The effect of the vibrational and translational energies of ionic reactant on the reaction C3H4++NH3.RAR.C3H3+NH4+.

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