Temperature effects on CD spectra of .ALPHA.-cyclodextrin complexes with m- and p-nitrophenol.
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The CD spectra of α-cyclodextrin complexes with <I>m</I>- and <I>p</I>-nitrophenol were measured at 10, 30, 50, and 70 °C in aqueous solutions of various α-cyclodextrin concentrations. The CD intensity of both complexes was decreased to 14–61% of the intensity measured at 10 °C with the increase of temperature to 70 °C, but no significant change was observed in the spectral shape. The thermodynamic parameters for the complex formation were determined.
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