Effect of diffusion layers on bi-ionic potentials acros liquid ion-exchange membranes.

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概要

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• In a bi-ionic system in which a liquid membrane is interposed between aqueous solutions containing different counterions, the solution composition is often not maintained uniform right up to the membrane–solution interface owing to the presence of diffusion layers adjacent to the interface. Taking the effect of the diffusion layers into account, an expression is derived for the bi-ionic potential across a membrane having completely dissociated ion-exchange sites and counterions. The expression contains as an empirical parameter the ratio between the thicknesses of the diffusion layers at the solution and membrane sides of the interface. The expression is found to agree with experimental data, with the parameter given a single value.

• 公益社団法人 日本化学会の論文

著者

• Yoshida Nobuo

  Department of Chemistry, Faculty of Science, Kyushu University

• Yoshida Nobuo

  Department of Applied Analytical Chemistry, Faculty of Engineering, Kyushu University

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