Vibrational spectra and normal coordinate calculations for methyl-1-propynylmercury(II) and its deuterated analogues.

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概要

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• Infrared spectra (4000–80 cm<SUP>−1</SUP>) of CH<SUB>3</SUB>HgC≡CCH<SUB>3</SUB>, CD<SUB>3</SUB>HgC≡CCH<SUB>3</SUB>, CH<SUB>3</SUB>HgC≡CCD<SUB>3</SUB>, and CD<SUB>3</SUB>HgC≡CCD<SUB>3</SUB> have been obtained in carbon tetrachloride, carbon disulfide and benzene solutions, as well as in the solid state at liquid nitrogen temperature. Raman spectra (4000–0 cm<SUP>−1</SUP>) have also been recorded on benzene solutions and on solids at room temperature. Assignments for all the fundamentals have been made assuming C<SUB>3v</SUB> molecular symmetry. Normal coordinate calculations have been carried out in order to confirm the proposed assignments.

• 公益社団法人 日本化学会の論文

著者

• Aida Koyo

  Department of Applied Science, Faculty of Engineering, Tohoku University

関連論文

• Vibrational spectra and normal coordinate calculations for trimethylgermane.
• Vibrational spectra and normal coordinate calculations for trimethylsilane.
• Vibrational spectra and normal coordinate calculations for methyl-1-propynylmercury(II) and its deuterated analogues.

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