Rare earth complexes of 1-(2-pyridylazo)-2-naphthol.

スポンサーリンク

概要

• 論文の詳細を見る

• The rare earth complexes of 1-(2-pyridylazo)-2-naphthol (PAN=Hpan) are prepared in the solid state. The analytical, molecular weight and differential thermal analysis data of the complexes indicated the metal-ligand ratio as 1:3 with the general formulae Ln(pan)<SUB>3</SUB>·H<SUB>2</SUB>O (Ln=Pr<SUP>3+</SUP>, Nd<SUP>3+</SUP>, and Sm<SUP>3+</SUP>) and Ln(pan)<SUB>3</SUB> (Ln=La<SUP>3+</SUP>, Eu<SUP>3+</SUP>, Gd<SUP>3+</SUP>, Tb<SUP>3+</SUP>, Dy<SUP>3+</SUP>, Ho<SUP>3+</SUP>, Er<SUP>3+</SUP>, and Yb<SUP>3+</SUP>). Based on IR, UV, and visible absorption spectra, electrical conductance and magnetic susceptibility data, an octahedral structure having the metal ion bonded through nitrogen of azo and oxygen of carbonyl groups of the ligand has been postulated to these complexes.

• 公益社団法人 日本化学会の論文

著者

• Agarwala Umesh

  Department of Chemistry, Indian Institute of Technology

• Satyanarayana D.

  Department of Chemistry, Andhra University

• Rao I.

  Department of Chemistry, Andhra University

関連論文

• Rare earth complexes of 1-(2-pyridylazo)-2-naphthol.
• In situ trapping of NO. A generalized method for the synthesis of metal nitrosyls.

スポンサーリンク