Binary phase chlorination of aromatic hydrocarbons with solid copper(II) chloride: Reaction mechanism.

スポンサーリンク

概要

• 論文の詳細を見る

• Anthracene is selectively chlorinated with solid copper(II) chloride to give a quantitative yield of 9-chloroanthracene. The tentative reaction mechanisms so far proposed fail to explain the nonreactivity of some other hydrocarbon homologues, <I>e.g</I>. naphthalene and phenanthrene, toward copper(II) chloride. The present study revealed that the oxidative half-wave potentials (<I>E</I><SUB>1⁄2ox</SUB>) of all reactive hydrocarbon homologues were less than 1.26 V. On the basis of this finding we postulate a reaction mechanism involving one electron transfer from hydrocarbon to copper(II) chloride.

• 公益社団法人 日本化学会の論文

著者

• Tanimoto Iwao

  Laboratory of Chemistry, Faculty of Home Economics, Kyoto. Women's University

関連論文

• Binary phase chlorination of aromatic hydrocarbons with solid copper(II) chloride: Reaction mechanism.

スポンサーリンク