Carbon-13 NMR spectra of di-t-alkyl ethers and related hindered ethers.

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概要

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• The C-13 NMR spectra of hindered <I>t</I>-alkyl ethers and dineopentyl ether have been presented and the electronic and steric effects discussed. The resonances for the α-, methylene β-, and methyl β-carbons of di-<I>t</I>-alkyl ethers shifted downfield by +45, +1.2, and −0.2 ppm, respectively, relative to the corresponding alkanes.

• 公益社団法人 日本化学会の論文

著者

• Masada Hiromitsu

  Department Of Chemistry And Chemical Engineering Faculty Of Technology Kanazawa University

• Murotani Yoshiharu

  Department of Industrial Chemistry, Faculty of Engineering, Kanazawa University

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• Carbon-13 NMR spectra of di-t-alkyl ethers and related hindered ethers.
• Synthesis of hindered t-alkyl ethers.

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