Monolayers of Branched-Chain Fatty Acids. II. α-Aromatic Substituted Fatty Acids
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(1) Force-area relations for 2-phenyl-, 2-(α-naphthyl)-, 2-benzyl- and 2-(α-naphthomethyl)-<I>n</I>-fatty acids have been investigated.<BR>(2) Force-area curves are characteristic to each of the four series, showing that the length of alkyl chains in the molecules has only a minor effect upon the curves.<BR>(3) Influence of <I>p</I>H on the force-area curves, so far examined, is shown to be similar to other fatty acids.<BR>(4) It was concluded that the aromatic ring in the α-position of the fatty acids has such an orientation that the plane of the aromatic ring is placed perpendicular to the water surface.<BR>(5) Film properties seem to have no direct relation to the antibacterial activity of these compounds, and some of the regularities for the activity are discussed.
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