The Radiation-Induced Addition of Acetaldehyde to Isobutylene

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概要

• 論文の詳細を見る

• The radiation-induced addition of acetalde-hyde to isobutylene has been found to proceed at room temperature; the <I>G</I>(telomer)'s are smaller by one or two orders of magnitude than those when ethylene or propylene is adopted as the taxogen, and they increase markedly with the temperature, reaching a maximum at 110∼150°C.<BR>It has been shown from the gas chromato-graphic and NMR analyses of the telomer produced that the radical chain mechanism proposed in former papers by the present authors is reasonable, although minor products seem to be formed in accordance to an ionic mechanism.<BR>It has been found that the <I>G</I> values of all the telomers decrease in the presence of several solid materials, suggesting the catalytic decomposition of acetyl and other intermediate radicals.

• 社団法人 日本化学会の論文

著者

• Hirota Kozo

  Japanese Association for Radiation Research on Polymers Osaka Laboratory

• Hatada Motoyoshi

  Japanese Association for Radiation Research on Polymers Osaka Laboratory

• Iizuka S.

  Japanese Association for Radiation Research on Polymers Osaka Laboratory

• Iizuka Shinji

  Japanese Association for Radiation Research on Polymers Osaka Laboratory

関連論文

• The Radiation-Induced Addition of Acetaldehyde to Isobutylene

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