The Menschutkin Reaction in Liquid Sulfur Dioxide

スポンサーリンク

概要

• 論文の詳細を見る

• 1) The Menschutkin reaction (reaction of methyl, ethyl or isopropyl iodide with pyridine, dimethylaniline or dimethyl-<I>o</I>-toluidine) has been carried out in liquid sulfur dioxide. The reaction rate has been compared with those in other commonly used solvents.<BR>2) The reaction rate in liquid sulfur dioxide is the slowest, whereas the previously performed reactions such as the Beckmann rearrangement and the cationic polymerization in this solvent were the fastest among the solvents ordinarily used.<BR>3) The reason for such a discrepancy has been discussed. Importance of the <I>Bare</I> (or unsolvated) ion or species in an ionic reaction is presented.

• 社団法人 日本化学会の論文

著者

• Tokura N.

  The Chemical Research Institute of Non-Aqueous Solutions

• Kondo Yasuhiko

  The Chemical Research Institute of Non-Aqueous Solutions Tohoku University

関連論文

• Effect of Added Solvents on the Radical Polymerization of Acrylonitrile in Liquid Sulfur Dioxide
• Radical Polymerization of Styrene in Liquid Sulfur Dioxide
• Isomerization of Cyclohexyl Phenyl Ketoxirne in Liquid Sulfur Dioxide
• The Cationic Copolymerization of Styrene and p-Brornostyrene in Liquid Sulfur Dioxide
• The Beckmann Rearrangement of 1,2-Cyclohexane-dione Dioxime in Liquid Sulfur Dioxide
• The Reactions of 1, 2-Cyclopentanedione Dioxime and of 1, 2, 3-and 1,3,5-Cyclohexanetrione Trioximes in Liquid Sulfur Dioxide
• The Menschutkin Reaction in Liquid Sulfur Dioxide
• Solvent Effect on the Rearrangement of Cyclohexanoneoxime-p-toluenesulfonate. The Ionizing Power of Liquid Sulfur Dioxide
• The Reaction of Isobutene with Chloromethyl Methyl Ether in Liquid Sulfur Dioxide
• Effect of Solvation on the Menschutkin Reaction in Liquid Sulfur Dioxide

スポンサーリンク