The Tracer Study of the Reactions of Diphenyl Sulfone and Diphenyl Sulfoxide with Sulfur

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概要

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• Diphenyl sulfoxide-<SUP>35</SUP>S was reduced to the sulfide-<SUP>35</SUP>S nearly quantitatively by heating with sulfur at 280°C, while diphenyl sulfone did not react with sulfur at the same temperature. At around 300°C, diphenyl sulfone-<SUP>35</SUP>S started to react with sulfur and gave diphenyl sulride that lost nearly 75% of the original activity of <SUP>35</SUP>S of the sulfone used. The main reaction of the sulfone was found not to be reduction, but substitution involving induced C-S cleavage and replacement with sulfur chain.

• 社団法人 日本化学会の論文

著者

• Oae S.

  Department of Chemistry Radiation Center of Osaka Prefecture

• Kawamura Shunichi

  Department of Chemistry Radiation Center of Osaka Prefecture

関連論文

• The Mechanism of Azoxybenzene Formation
• Mechanisms of the Wallach Rearrangement
• The Tracer Study of the Reactions of Diphenyl Sulfone and Diphenyl Sulfoxide with Sulfur

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