Thermal and Radiation Oxidations of Benzene to Phenol in Aqueous Solutions Containing Metal Ions at Elevated Temperatures. III. The Effect of Copper Ions
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概要
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The yield of phenol increases abruptly above 170°C in the cupric sulfate solutions. When the solutions contain copper metal pieces, phenol is produced, even below 160°C, regardless of irradiation or non-irradiation. On the other hand, scarcely any phenol is produced in the cupric-ferric sulfate solution, even at 180°C. These facts are to be attributed to the fast rate of cuprous oxidation by oxygen.
- 社団法人 日本化学会の論文
著者
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Suzuki Nobutake
Japan Atomic Energy Research Institute
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Hotta H.
Japan Atomic Energy Research Institute
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Terakawa Akira
Japan Atomic Energy Research Institute
関連論文
- Oxidation of Ferrous Ions in Aqueous Solutions by Cobalt-60 Gamma Rays. III. The Effect of Cupric Ion in Air-free Acidic Solutions
- Thermal and Radiation Oxidations of Benzene to Phenol in Aqueous Solutions Containing Metal Ions at Elevated Temperatures. III. The Effect of Copper Ions
- Oxidation of Ferrous Ions in Aqueous Solutions by Cobalt-60 Gamma Rays. II. Effect of Anions at High Dose
- The Radiation-induced Decoloration of Azo Dye in Aqueous Solutions
- The radiolysis of anthraquinone dye in aqueous solutions.
- The effects of halide ions on the radiation-induced decoloration of azo and anthraquinone dyes in N2O-saturated aqueous solutions.