Electrolytically Regenerated Ceric Sulfate for the Oxidation of Organic Compounds. I. Oxidation of <I>p</I>-Xylene to <I>p</I>-Tolualdehyde
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概要
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1. The current efficiency for the oxidation of cerous sulfate in sulfuric acid at a lead dioxide in an undivided cell was generally found to be 70%.<BR>2. By using a paste of cerous sulfate in sulfuric acid, ceric sulfate reagent is obtained in a concentrated form.<BR>3. A kinetic study of the oxidation of <I>p</I>-xylene by ceric sulfate is described and apparent energy of activation is calculated.<BR>4. The process of oxidation of <I>p</I>-xylene to <I>p</I>-tolualdehyde is made cyclic and continuous by regeneration of ceric sulfate at a lead dioxide anode.
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