On the Temperature Dependence of Spectra of Solvated Anions
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概要
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The effect of temperature on the ultraviolet spectra of solvated anions is examined experimentally and theoretically. The shift of the spectrum to the longer wavelength with increasing temperature can be explained in terms of the oscillator model of the solvent molecules. This corresponds to the increase of the ionic radii (or the radius of the cavity) with the temperature rise.
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