Iodine-Catalyzed Thermal <I>cis-trans</I> Isomerization of Stilbene
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概要
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The iodine-catalyzed thermal cis → trans conversion of stilbene has been studied kinetically in <I>n</I>-hexane in temperature range 62.0∼68.8°C. The reaction rate obtained spectrophotometrically has been found to be proportional to the concentration of <I>cis</I>-stilbene and to the square root of iodine concentration. The overall activation energy has been found to be 25 kcal./mol. The results have been interpreted in terms of the thermal dissociation of iodine molecules followed by the formation of a transient complex between <I>cis</I>-stilbene and atomic iodine.
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