Halogen Substitution in Liquid Sulfur Dioxide. I. Formation of Alkyl Halides from Alcohols and Halogens

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概要

• 論文の詳細を見る

• The reaction between aliphatic alcohols and bromine in liquid sulfur dioxide at room temperature was investigated in order to obtain further information concerning the behavior of bromine in liquid sulfur dioxide. The reactivity of the alcohols increased in the order of primary <secondary<tertiary.<BR>In addition to alkyl bromides, higher boiling bromides were also produced. The latter resulted from further elimination, dimerization and bromine addition. The rather complicated feature of the bromination is attributable to the presence of sulfur trioxide secondarily formed in the reaction mixture.

• 社団法人 日本化学会の論文

著者

• Tokura Niichiro

  Chemical Research Institute of Non-aqueous Solutions Tohoku University

• Tada Ritsuro

  Chemical Research Institute of Non-aqueous Solutions Tohoku University

• Igarashi Ryoichi

  Chemical Research Institute of Non-aqueous Solutions Tohoku University

• Tokura N.

  Chemical Research Institute of Non-aqueous Solutions Tohoku University

関連論文

• Halogen Substitution in Liquid Sulfur Dioxide. I. Formation of Alkyl Halides from Alcohols and Halogens
• The Beckmann Rearrangement of the Geometrical Isomers of Cyclohexyl Phenyl Ketoxime in Liquid Sulfur Dioxide
• Retardation Effect Induced by Pyridine in the Radical Copolymerization of Styrene and Liquid Sulfur Dioxide

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