Studies on Organic Peroxides. VI. Thermal Analysis of the Decomposition of Benzoyl Peroxide by Ferrous Ion
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概要
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The thermal analysis method was applied to follow the rate of the decomposition of benzoyl peroxide catalysed by ferrous ion in methanol, ethanol, <I>n</I>-propanol and <I>n</I>-butanol.<BR>The apparent rates were of the first order and no fundamental difference in the reaction mechanism was observed among these alcohols. However, the reaction rates in methanol were much slower than in three other alcohols. Solvent effects on the reaction rate were discussed.<BR>Linear enthalpy-entropy relationship was deduced, assuming that the free energy of activation is the linear function of an intensity factor in a series of reactions. This was found to be true in our case.
- 社団法人 日本化学会の論文
著者
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Nishimura Norio
Department Of Chemistry Faculty Of Science Okayama University
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Hasegawa S.
Department of Internal Medicine (II), Niigata University School of Medicine
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Miura Kimpei
Department of Chemistry Faculty of Science Okayama University
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