Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-N-oxyl Organocatalyst

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概要

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• By utilizing a specific solvent and highly active 2-azaadamantane-N-oxyl (AZADO) as an organocatalyst, we have improved the recycling protocol of the adamatane reagent 1 to be faster and more operationally simple for the hypervalent iodine/nitroxyl radical mediated alcohol oxidation. This very mild system can efficiently mediate the oxidation of a range of alcohols to carbonyl compounds with a broad substrate scope, and after the reactions, the reduced adamantane tetraiodide 1′, which automatically precipitated from the reaction mixtures as the reactions progresses, could be directly recovered by filtration.

• 公益社団法人　日本薬学会の論文

著者

• Dohi Toshifumi

  College of Pharmaceutical Sciences, Ritsumeikan University

• Kita Yasuyuki

  College of Pharmaceutical Sciences, Ritsumeikan University

• Kita Yasuyuki

  College Of Pharmaceutical Sciences Ritsumeikan University

• Dohi Toshifumi

  College Of Pharmaceutical Sciences Ritsumeikan University

• Ito Motoki

  College of Pharmaceutical Sciences, Ritsumeikan University

• Kamitanaka Tohru

  College of Pharmaceutical Sciences, Ritsumeikan University

• Mochizuki Eisuke

  College of Pharmaceutical Sciences, Ritsumeikan University

関連論文

• A Facile and Clean Direct Cyanation of Heteroaromatic Compounds Using a Recyclable Hypervalent Iodine(III) Reagent
• Recycling and Catalytic Approaches for the Development of a Rare-Metal-Free Synthetic Method Using Hypervalent Iodine Reagent
• Clean and Direct Synthesis of α,α′-Bithiophenes and Bipyrroles by Metal-Free Oxidative Coupling Using Recyclable Hypervalent Iodine(III) Reagents
• Hypervalent Iodine Induced Metal-Free C-H Cross Couplings to Biaryls
• Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-N-oxyl Organocatalyst

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